Past Notices (~2021)

Mar 9, 2022
A paper entitled “
Liquid Bisazobenzenes as Molecular Solar Thermal Fuel with Enhanced Energy Density”
has been published online in Chem. Lett (Open Access).
Jan 22, 2022
A paper entitled “Heavy metal-free visible-to-UV photon upconversion with over 20% efficiency sensitized by a ketocoumarin derivative”
has been published in J. Mater. Chem. C.
Jan 5, 2022
A paper entitled “Near-Infrared Vapochromism in Lipid-Packaged Mixed-Valence Coordination Polymers” has been published in Chem. Commun.
Dec 24, 2021
A paper entitled “Triplet Dynamic Nuclear Polarization of Guest Molecules through Induced Fit in a Flexible Metal-Organic Framework”has been published in Angew. Chem. Int. Ed.
June 7, 2021
A paper entitled “High seebeck coefficient in middle-temperature thermocell with deep eutectic solvent” has been published in
Sci Rep.
May 13, 2021
A paper entitled “Design Guidelines to Elongate Spin–Lattice Relaxation Times of Porphyrins with Large Triplet Electron Polarization” has been published in J. Phys. Chem. A.
May 11, 2021
A paper entitled “High Positive Seebeck Coefficient of Aqueous I–/I3– Thermocells Based on Host–Guest Interactions and LCST Behavior of PEGylated α-Cyclodextrin” has been published in ACS Appl. Energy Mater.
March 29, 2021
A paper entitled “Ionic Charge-Transfer Liquid Crystals Formed by Alternating Supramolecular Copolymerization of Liquid π-Donors and TCNQ” has been published in Frontiers in Chemistry.
July 14th, 2020
A paper entitled “Photon Upconverting Solid Films with Improved Efficiency for Endowing Near‐Infrared Sensitivity to Perovskite Solar Cells” has been published in ChemPhotoChem.
June 22nd, 2020
A paper entitled “Number of Surface-Attached Acceptors on a Quantum Dot Impacts Energy Transfer and Photon Upconversion Efficiencies” has been published in ACS Photon.
May 16th, 2020
A paper entitled “Leaping across the visible range: near-infrared-to-violet photon upconversion employing a silyl-substituted anthracene” has been published in Chem. Commun.
May 2nd, 2020
A review paper entitled “Materials chemistry of triplet dynamic nuclear polarization” has been published in Chem. Commun.
Apr 14th, 2020
Prof. Kimizuka was appointed as Research Supervisor of JST CREST program “Precice arrangement toward functionality“.
Mar 4th, 2020
A paper entitled “A Liquid Arylazopyrazole Derivative as Molecular Solar Thermal Fuel with Long-term Thermal Stability” has been published in Chem. Lett.
Jan 21st, 2020
Prof. Yanai starts to serve an Associate Editor of Chemical Physics Reviews, AIP.
Mar 4th, 2020
A paper entitled “Triplet dynamic nuclear polarization of crystalline ice using water-soluble polarizing agents” has been published in Chem. Commun.
Feb 25th, 2020
A Minereview entitled “Stimuli-Responsive Molecular Photon Upconversion” has been published in Angew. Chem. Int. Ed. 
Jan 21st, 2020
Prof. Yanai was selected as one of MSDE Emerging Investigators 2020 (RSC) and a paper entitled “Visible-to-UV photon upconversion in air-saturated water by multicomponent co-assembly” has been published in Mol. Syst. Des. Eng. for this occasion.
Jan 21st, 2020
Prof. Yanai joined the Early Career Advisory Board of ChemNanoMat, Wiley.
Jan 10th, 2020
A paper entitled “Polar Switching of Dipolar Molecules Induced by Solid Dispersion-to-Organogel Phase Transition” has been published in Chem. Lett.
Dec 28th, 2019
A paper entitled “Polar Switching of Dipolar Molecules Confined in Submicron- and Micron-sized Pores in Polymer Films” has been published in Chem. Lett.
Dec 27th, 2019
A paper entitled “Enhanced Electric Polarization and Polar Switching of Dipolar Aromatic Liquids Confined in Supramolecular Gel Networks” has been published in J. Am. Chem. Soc.
Nov 29th, 2019
A papaer entitled “Aqueous Photon Upconversion by Anionic Acceptors Self-Assembled on Cationic Bilayer Membranes with a Long Triplet Lifetime” has been pubished in Organic Materials.
Nov 27th, 2019
A paper entitled “Visible-to-UV Photon Upconversion in Nanostructured Chromophoric Ionic Liquids” has been published in ChemistryOpen. 
Sep 29th, 2019
A paper entitled “Near-infrared optogenetic genome engineering based on photon upconversion hydrogels” has been published in Angew. Chem. Int. Ed. 
Jul 6th, 2019
A paper entitled “Visible-to-UV Photon Upconversion Sensitized by Lead Halide Perovskite Nanocrystals” has been published in Chem. Lett. 
Jun 27th, 2019
A paper entitled “Triplet dynamic nuclear polarization of nanocrystals dispersed in water at room temperature” has been published in Phys. Chem. Chem. Phys. 
May 6th, 2019
Prof. Nobuhiro Yanai received The Wiley Young Researcher Award conferred on early career researchers in the Asia-Pacific region. He was selected among hundreds of applications.
Apr 11th, 2019
A paper entitled “Liquid Crystalline Microspheres of Azobenzene Amphiphiles formed by Thermally Induced pH Changes in Binary Water-Hydrolytic Ionic Liquid Media” has been published in Chem. Commun.
Apr 1st, 2019
A paper entitled “Non-Pentacene Polarizing Agents with Improved Air-Stability for Triplet Dynamic Nuclear Polarization at Room Temperature” has been published in J. Phys. Chem. Lett. 
Mar 27th, 2019
A review entitled “Recent Progress in Photon Upconverting Gels” has been published in Gels as the part of Special Issue “Challenges for Gel Materials in the 21st Century” edited by Prof. David Díaz Díaz.
Feb 7th, 2019 
A collaboration work with Angelo Monguzzi & Francesco Meinardi group about upconversion in MOF at very low excitation intensity was published in Nano Lett.
Feb 3rd, 2019
A paper entitled “Supramolecular Crowding Can Avoid Oxygen Quenching of Photon Upconversion in Water” has been published in Chem.-Eur. J.
Oct 22nd, 2018
A paper entitled “Hexakis(2,3,6-tri-O-methyl)-α-cyclodextrin–I5− complex in aqueous I−/I3− thermocells and enhancement in the Seebeck coefficient” has been published in Chem. Sci.
Jan 2nd, 2019
A paper entitled “Oligo(ethylene glycol)/alkyl‐modified chromophore assemblies for photon upconversion in water” has been published in Chem. Asian J.
Nov 11th, 2018
A paper entitled “Dynamic Nuclear Polarization of Metal–Organic Frameworks Using Photoexcited Triplet Electrons” has been published in J. Am. Chem. Soc.
July 30th, 2018
A Perspective entitled “Solid-State Photon Upconversion Materials: Structural Integrity and Triplet/Singlet Dual Energy Migration” has been published in J. Phys. Chem. Lett.
July 27th, 2018
A paper entitled “A Simple and Versatile Platform for Air-Tolerant Photon Upconverting Hydrogels by Biopolymer-Surfactant-Chromophore Co-assembly” has been published in J. Am. Chem. Soc.
April 18th, 2018
A paper entitled “Donor-Acceptor-Collector Ternary Crystalline Films for Efficient Solid-State Photon Upconversion” has been published in J. Am. Chem. Soc.
June 1st, 2018 
Our paper published in J. Mater. Chem. C was selected as a Cover Picture.
May 29th, 2018
A new collaboration work with David Díaz Díaz group about photoredox catalysis in supramolecualr gel was published in J. Org. Chem.
April 18th, 2018
A paper entitled “Aggregation-Free Sensitizer Dispersion in Rigid Ionic Crystals for Efficient Solid-State Photon Upconversion and Demonstration of Defect Effects” has been published in J. Mater. Chem. C.
April 11th, 2018
A paper entitled “Translating MOF chemistry into supramolecular chemistry: soluble coordination nanofibers showing efficient photon upconversion” has been published in Chem. Commun.
February 27th, 2018
A paper entitled “Hybridizing semiconductor nanocrystals with metal-organic frameworks for visible and near-infrared photon upconversion” has been published in Dalton Trans.
This is the invited contribution to theThemed Issue on “Metal Complexes and Nanoparticles for Energy Upconversion”.
February 23th, 2018
A paper entitled “Specific Uniaxial Self-assembly of Columnar Perylene Liquid Crystals in Au Nanofin Arrays” has been published as “Editor’s Choice” in Chem. Lett.
February 19th, 2018 
Our paper published in Angew. Chem. Int. Ed. was selected as a Cover Picture.
January 24th, 2018 A paper entitled “Stimuli-Responsive Dual-color Photon Upconversion: an S-T absorption sensitizer in a soft luminescent cyclophane” has been published in Angew. Chem. Int. Ed. 
December 31st, 2017 
A paper entitled “Synthesis and Electric Properties of a Two-Dimensional Metal-Organic Framework based on Phthalocyanine” has been published in Chem.-Eur. J. 
December 12th, 2017 
A new collaboration work with Angelo Monguzzi & Francesco Meinardi group about highly fluorescent MOF-polymer nanocomposites was published in Nano Lett.
November 4th, 2017 
A paper entitled “Nonpolar-to-Polar Phase Transition of a Chiral Ionic Plastic Crystal and Switch of the Rotation Symmetry” has been published in J. Am. Chem. Soc. 
November 6th, 2017 
A paper entitled “Kinetically controlled crystal growth approach to enhance triplet energy migration-based photon upconversion” has been published in J. Photon. Energy. 
This is the invited contribution to the special issue on “spectral management for renewable energy conversion” focusing on photon upconversion and singlet fission.
November 3rd, 2017 
A paper entitled “Two-dimensional structural ordering in a chromophoric ionic liquid for triplet energy migration-based photon upconversion” has been published in Phys. Chem. Phys. Chem. 
November 3rd, 2017 
A paper entitled “Reentrant Gel-Sol-Gel Transition of a Lipophilic Co(II) Coordination Polymer” has been published in Chem. Lett. 
September 21st, 2017 
A review entitled “New Triplet Sensitization Routes for Photon Upconversion: Thermally Activated Delayed Fluorescence Molecules, Inorganic Nanocrystals, and Singlet-to-Triplet Absorption” has been published in Acc. Chem. Res. 
September 2nd, 2017 
A paper entitled “Sensitizer-Free Photon Upconversion in Single-Component Brominated Aromatic Crystals” has been published in ChemistrySelect. 
June 9th, 2017 
A paper entitled “Triplet Sensitization by Perovskite Nanocrystals for Photon Upconversion” has been published in Chem. Commun. 
May 2nd, 2017 
A paper entitled “Near infrared-to-blue photon upconversion by exploiting direct S-T absorption of a molecular sensitizer” has been published in J. Mater. Chem. C .
May 1st, 2017 
Dr. Shogo Amemori has started his carrier as an assistant professor at Kanazawa Univerisity. Good luck!
January 15th, 2017 
A paper entitled “Photoresponsive Nanosheets of Polyoxometalates Formed by Controlled Self-Assembly Pathways” has been published in Angew. Chem. Int. Ed. and selected as “Hot Paper”.
January 12th, 2017
A papaer entitiled “Self-assembly of Oligo(ethylene oxide)-linked Diammonium Ions with Polyoxometalates into Ordered Polyhedron Nanocrystals in Aqueous Media” has been published in Chemistry Letters and selected as “Editors Choice”.
October 19th, 2016
An Invited Feature Article “Photon Upconversion and Molecular Solar Energy Storage by Maximizing the Potential of Molecular Self-Assembly” has been published online in Langmuir.
September 28th, 2016
A paper entitled ” Hierarchical Self-Assembly of Luminescent Tartrate-Bridged Chiral Binuclear Tb(III) Complexes in Ethanol” has been published online in Langmuir.
August 16th, 2016
A paper entitled “Ferroelectric Coordination Polymers Self-Assembled from Mesogenic Zinc(II)Porphyrin and Dipolar Bridging Ligands” has been published online in Chem. Eur. J.
August 10th, 2016
A paper entitled “Supramolecular Thermo-Electrochemical Cells: Enhanced Thermoelectric Performance by Host-Guest Complexation and Salt-Induced Crystallization” has been published online in J. Am. Chem. Soc.
August 10th, 2016
A paper entitled “All-or-None Switching of Photon Upconversion in Self-Assembled Organogel Systems” has been published online in Faraday Discussions.
May 10th, 2016
A paper entitled “Near Infrared-to-Visible Photon Upconversion Sensitized by a Metal Complex with Spin-Forbidden yet Strong S0-T1 Absorption ” has been published online in J. Am. Chem. Soc.
May 23rd, 2016
A paper entitled “Increased Vis-to-UV upconversion performance by energy level matching between a TADF donor and high triplet energy acceptors” has been published online in J. Mater. Chem. C.
This is a result of collaboration with Prof. Chihaya Adachi and Dr. Ryota Kabe (Kyushu University).
May 10th, 2016
A paper entitled “Preorganized Chromophores Facilitate Triplet Energy Migration, Annihilation and Upconverted Singlet Energy Collection” has been published online in J. Am. Chem. Soc.
This is a result of collaboration with Prof. Steve Granick and Dr. Melinda Sindoro (University of Illinois at Urbana-Chambain) through JSPS-NSF ICC project.
April 29th, 2016
A paper entitled “Employing Core-Shell Quantum Dots as Triplet Sensitizer for Photon Upconversion” has been published online in Chemistry-A European Journal.
April 18th, 2016
A paper entitled “Trplet energy migration-based photon upconversion by amphiphilic molecular assemblies in aerated water” has been published online in Chem. Sci.
March 7th, 2016
A review paper entitled “Recent Emergence of Photon Upconversion based on Triplet Energy Migration in Molecular Assemblies” has been published online as a Feature Article in Chem. Commun.
January 8th, 2016
A paper entitled “Molecularly Dispersed Donors in Acceptor Molecular Crystals for Photon Upconversion under Low Excitation Intensity” has been published online in Chemistry-A European Journal.
December 18th, 2015
Mr. Keita Ishiba (D2) received a student poster award at Pacifichem 2015 (Honolulu).
Reversible Photo-Induced Liquefaction and Crystallization of Ionic Azobenzene Derivatives with Photon Energy Storage Characteristics
November 6th, 2015
Dr. Rakesh Kumar Gupta (Banaras Hindu University, India) joined our group as a JSPS postdoc.
Welcome to our group and let’s enjoy new science!
August 19th, 2015
A paper entitled “Photon-Upconverting Ionic Liquids: Effective Triplet Energy Migration in Contiguous Ionic Chromophore Arrays” has been published online in Angew. Chem. Int. Ed.
August 3rd, 2015
A paper entitled “Fast and Long-range Triplet Exciton Diffusion in Metal-organic Frameworks for Photon Upconversion at Ultralow Excitation Power” has been published online in Nature Materials.
This work was highlighted in News and VIews in the same issue.
August 3rd, 2015
A paper entitled “Metallonaphthalocyanines as Triplet Sensitisers for Near-Infrared Photon Upconversion beyond 850nm” has been published online in PhysChemChemPhys.
July 6th, 2015
A paper entitled “Interlocked dimerization of C3-symmetrical boron difluoride complex: designing non-cooperative supramolecular materials for luminescent thin films” has been published online in RSC Advances.
June 9th, 2015
A paper entitled “Highly Efficient Photon Upconversion in Self-Assembled Light-Harvesting Molecular Systems” has been published on line in Scientific
Reports.
May 15th, 2015
A paper entitled “Aggregation-Induced Photon Upconversion through Control of the Triplet Energy Landscapes of the Solution and Solid States” has been published on line in Angew. Chem. Int. Ed.
April 9th, 2015
A paper entitled “Photoinduced Crystallization in Ionic Liquids: Photodimerization-induced Equilibrium Shift and Crystal Patterning” has been published online in Chem. Lett.
April 3rd, 2015
New members joined our group. Let’s enjoy science!
January 19th, 2015
A paper entitled “Photon Upconversion in Supramolecular Gel Matrixes: Spontaneous Acculumation of Light-Harvesting Donor-Acceptor Arrays in Nanofibers and Acquired Air Stability” has been published online in J. Am. Chem. Soc.
December 14th, 2014
Dr.Tejwant Singh Kang (Guru Nanak Dev University, India) joined our group.
He will stay for Two weeks. Welcome back Tej-san!!
December 5th, 2014
A paper entitled “Photoliquefiable Ionic Crystals: A Phase Crossover Approach for Photon Energy Storage Materials with Functional Multiplicity” has been published online in Angew. Chem. Int. Ed.
November 16th, 2014
Dr.LIU Jing (SHAANXI NORMAL UNIVERSITY, China) joined our group.
She will stay for Two weeks.
November 5th, 2014
A paper entitled ” Light-Reducible Dissipative Nanostructures Formed at the Solid-Liquid Interface” has been published online in Langmuir.
October 30th, 2014
A paper entitled “A Liquid Azobenzene as Solvent-Free Solar Thermal Fuel”
has been publisehd online in Chem. Commun.
October 17th, 2014
Dr. Nobuhiro Yanai received “The Award for Encouragement of Research”
in IUMRS-ICA2014. Congratulations!
October 7th, 2014
Dr. Deepak Asthana (Jawaharlal Nehru University, India) joined our group as a JSPS postdoc.
Welcome to our group and let’s enjoy new science!
October 2nd, 2014
Ms. Melinda SINDORO (The University of Illinois at Urbana-Champaign) joined our group. She will stay for Two months.
Welcome, Melinda!!
September 16th, 2014
A paper entitled “A bis-cyclometalated iridium complex as a benchmark
sensitizer for efficient visible-to-UV photon upconversion” has been
publisehd online in Chem. Commun.
April 3rd, 2014
New members joined our group. Let’s enjoy science!
February 21st, 2014
The 1st CMS International Symposium was held at Inamori Hall of the Inamori Center.
February 15th, 2014
A paper entitled “Self-Assembly of Azobenzene Bilayer Membranes in Binary Ionic Liquid-Water Nanostructured Media” has been published online as an ASAP Article in Langmuir.
February 12nd, 2014
Dr. Gustavo Fernández(Universität Würzburg) joined our group as an associate professor of CMS. Welcome, Gustavo!!
January 16th, 2014
Dr. Angelo Maria MONGUZZI (University of Milano-Bicocca) joined our group as a JSPS postdoc. Welcome, Angelo!!
December 12th, 2013
A paper entitled “Photon Upconverting Liquids:Marix-Free Molecular Photon-Upconverting Systems Functioning in Air” has been publisehd online in J. Am. Chem. Soc.
November 7th, 2013
A paper entitled “Spectroscopic Readout of Polyoxomethalates’ Molecular Information via Self-Assembly” has been publised online in Chem.Commun.
September 30th, 2013
A paper entitled “Controlled Self-Assembly and Luminescence Characteristics of Eu(III) Complexes in Bianry Aqueous/Organic Media” has been published online in Langmuir.
May 29th, 2013
A paper entitled “Redox-Active Microcapsules of Cytochrome c Formed at the Ionic Liquid-Water Interface” has been published online as an Advanced View Manuscript of Chemistr Letters.
April 16th, 2013
Prof. Kimizuka received “Prizes for Science and Technology” by the Minister of Education, Culture, Sports, Science and Technology.
April 4th, 2013
New members joined our group. Let’s enjoy science!
March 23th, 2013
Dr. Teppei Yamada received The CSJ Award for Young Chemists. Congratulations!
March 22th, 2013
A paper entitled “Controlled Formation of Microspheres from Ferrocene-Derivatized Amino Acids in Binary Aqueous-Organic Media” has been publised online as an Advanced View Manuscript of Chemistry Letters.
January 25th, 2013
Dr. Yanai received “the first prize of the Quadrant Award 2013”. Congratulations!
November 2nd, 2012
A paper entitled “Biopolymer-Encapsulated Protein Micocapsules Spontaneously Formed at the Ionic Liquid-Water Interface” has been published online as Just Acccepted Manuscripts to Biomolecules.
November 1st, 2012
Dr. Teppei Yamada and Dr. Nobuhiro Yanai have joined our group as CMS (Center for Molecular Systems) Associate Professor and Assistant Professor, respectively. Welcome to our group and let’s have fun.
September 28th, 2012
A paper entitled “Converting Molecular Information of Redox Coenzymes via Self-Assembly” has been published online in Chem.Commun.
September 6th, 2012
A paper by Dr. Tejwant Singh et.al. entitled “Ionic Liquids Induced Structural Changes of Bovine Serum Albumin in Aqueous Media: A Detailed Physicochemical and Spectroscopit Study” has been published online in J. Phys. Chem. B.
July 30th, 2012
A paper entitled “Electrochemically Controlled 2D Assembly of Paddle-Wheel Diruthenium Complexes on the Au(111) Surface and Identification of Their Rodox States” has been published online in J.Phys.Chem.C.
May 20th, 2012
Prof. Kimizuka received “The Award of the Society of Polymer Science, Japan” for our achievements on “Development of Functional Molecular Systems Based on Self-Assembly”
April 25th, 2012
A paper entitled “Controlled Self-Assembly of Amphiphiles in Ionic Liquids and the Formation of Ionogels by Molecular Tuning of Cohesive Energies” has been published online in Polymer Journal.
January 23th, 2012

A paper entitled ” Synthesis of TiO2 Nanocoral Structures in Ever-Changing Aqueous Reaction Systems” has been published online in Langmuir.

January 20th, 2012
Prof. Kazunori Matsuura received the JSPS PRIZE in FY2011 from the Japan Society for the Promotion of Science.
December 13th, 2011
A paper entitled “Controlled Polymerization and Self-Assembly of Halogen-Bridged Diruthenium Complexes in Organic Media and Their Dielectrophoretic Alignment” has been published online in J. Am. Chem. Soc.
December 1st, 2011
A paper entitled “Self-Assembly of Tubular Microstructures from Mixed-Valence Metal Complexes and Their Reversible Transformation by External Stimuli” has been published online in Angew. Chem. Int. Ed.
September 20th, 2011
A paper entitled “Conversion of Molecular Information by Luminescent Nanointerface Self-Assembled from Amphiphilic Tb(III) Complexes” has been published online as Just Accepted Manuscripts in J. Am. Chem. Soc.
May 6th, 2011
A paper entitled “Controlled Morphology and Photoreduction Characteristics of Polyoxomethalate(POM)/Lipid Complexes and the Effect of Hydrogen Bonding at Molecular Interfaces” has been published online in Chem. Commun.
January 10th, 2011
A paper entitled “Water/Ionic Liquid Interfaces as Fluid Scaffolds for the Two-Dimensional Self-Assembly of Charged Nanospheres” has been published online in Langmuir.
November 12th, 2010
A paper entitled “Self-Assembled Synthetic Viral Capsids from a 24-mer Viral Peptide Fragment” has been publishe online in Angew. Chem. Int. Ed.
October 14th, 2010
A paper entitled “Aqueous Nanospheres Self-Assembled from Hyperbranched Polymers and SIlver Ions: Molecular Inclusion and Photoreduction Characteristics” has been published online in Macromolecules.
August 20, 2010
A paper entitled “Trigonal Tryptophane-Zipper as a Novel Building Block for pH-Responding Peptide Nano-assemblies” has been published
on line in Chem. Commun..
August 15th, 2010
A paper entitled “Glutathione Nanospheres: Self-assembly of Conformation-regulated Trigonal-glutathiones in Water” has been published online
in Bull. Chem. Soc. Jpn., vol. 83, No. 8, 880886 (2010) .
June 19th, 2010
A paper entitled “Electrochemically Controlled Self-assembly of Lipophilic Fe(II)1,2,4-Triazole Complexes in Chloroform” has published online in Chem.Lett.
May 12th, 2010
A paper entitled “Selective Inclusion of Anionic Quantum Dots in Coordination Network Shells of Nucleotides and Lanthanide Ions” has published as an Advanced Article in Chem. Commun.
February 28th, 2010
A paper entitled “Switching On Luminescence in Nucleotide/Lanthanide Coordination Nanoparticles via Synergistic Interactions with a Cofactor Ligand” has published online in Chemistry – A European Journal.
February 6th, 2010
A paper entitled “Synthesis of Lipophilic Gold Nanosheets by Using Reducing Stabilizers and Their Reversible Transformation between Golden Solid” has published online in Chem. Lett.
January 14th, 2010
A paper entitled “Spin Crossover Characteristics of Nanofibrous FeII-1,2,4-Triazole Complexes in Liquid Crystals ” has published online in Chem.Commun.
November 17th, 2009
A paper entitled “Confining Molecules within Aqueous Coordination Nanoparticles by Adaptive Molecular Self-Assembly” has published online in Angew. Chem. Int. Ed.
September 16th, 2009
A paper entitled ” One-Pot Room Temperature Synthesis of Single-Crystalline Gold Nanocorollar in Water” has published online as ASAP article in J.Am.Chem.Soc.